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Phosphine

PH3

DESCRIPTION: Phosphine (PH3) is a colorless, highly toxic, flammable gas with an unpleasant odor similar to decaying fish. Phosphine should be considered pyrophoric in high concentrations and may form explosive mixtures with air.

APPLICATION: Phosphine is used in silicon processing as a phosphorus (N-type dopant) source in chemical vapor deposition (CVD) and ion implantation. Phosphine is also used in gallium arsenide as an ion implantation gas in the manufacture of light emitting diodes (LEDs).

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PHOSPHINE
GRADE ELECTRONIC VLSI SIGMA 3
Critical Assay 99.99% 99.999% 99.9996%
Meets SEMI Specification - SEMI C3.6-93 -
Nitrogen < 10 ppm < 1 ppm < 1 ppm
Oxygen < 3 ppm < 1 ppm < 0.1 ppm (+Ar)
Total Hydrocarbons (as CH4) < 3 ppm < 1 ppm < 0.1 ppm
Carbon Monoxide < 1 ppm < 1 ppm < 0.2 ppm
Carbon Dioxide < 10 ppm < 1 ppm < 0.2 ppm
Water < 1 ppm < 1 ppm < 1 ppm
Arsine < 10 ppm < 1 ppm < 1 ppm
Valve Material 316L SS 316L SS 316L SS
Valve Design Diaphragm Diaphragm Diaphragm
CGA/DISS Connection 350 350/632 350/632

 

  
Molecular Weight:
34.0
Specific Volume:
11.4 cf/lb @ NTP
Boiling Point:
-125.9°F @ 1atm
CAS No.:
7803-51-2
Hazards:
Inhalation and Flammability
Safety Data: LC50 Rat: 20 ppm
ACGIH - TLV: 0.3 ppm
ACGIH - STEL: 1 ppm
NIOSH IDLH: 50 ppm
Vapor Pressure Data:
310 psia@ 32 °F
499.7 psia @ 70 °F

 

PHOSPHINE          
Cylinder Data/Size D LB      
Internal Volume (liters): 2.4 0.4      
Contents in lbs (grams): 1 (454) 0.1 (45)      
Pressure @ 70°F (psig): 485 485      
RFO Size (inches): 0.007 0.010 0.014 0.020  
Maximum Flow (scf/h): 16.59 33.86 66.36 135.4  
Pressure (psia): 499.7        
DOT Label: White, Inhalation Hazard; Red, Flammable Gas UN Number: UN 2199
DOT Class: 2.3 Cylinder: Steel alloy
Recommended OmniGas® Panels: Purgable panel for toxic gases - Model No. 58PA200SVA
Shelf Life: 2 years

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