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Dichlorosilane

SiH2Cl2

DESCRIPTION: Dichlorosilane (SiH2Cl2) is a colorless, highly toxic, corrosive, flammable gas with a pungent and suffocating odor. Dichlorosilane may ignite spontaneously above 100°C. It becomes extremely corrosive in moist air, fuming and hydrolizing to form Hydrochloric Acid and polymeric siloxanes. Shipped as a liquefied gas under its own vapor pressure (9 psig @ 70°F).

APPLICATION: Dichlorosilane is a silicon precursor gas used in combination with ammonia for silicon nitride chemical vapor deposition (CVD). Dichlorosilane is also used for epitaxial silicon deposition.

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DICHLOROSILANE
GRADE EPITAXIAL SIGMA 3
Critical Assay 99.0% 99.7%
Meets SEMI Specification SEMI C3.31-94 -
Chlorosilanes < 1 % -
Monochlorosilane - < 800 ppmw
Trichlorosilanes - < 2000 ppmw
Inerts < 1 % < 0.1%
Carbon < 2 ppmw < 0.05 ppmw
Arsenic < 0.1 ppbw < 0.03 ppbw
Boron < 0.1ppbw < 0.02 ppbw
Iron < 10 ppbw < 3 ppbw
Aluminum < 0.1 ppbw < 0.04 ppbw
Phosphorus < 0.1 ppbw < 0.05 ppbw
Silicon Tetrachloride - < 300 ppmw
Resistivity > 150 ohm/cm > 400 ohm/cm
Valve Material 316L SS 316L SS
Valve Design Tied Diaphragm Tied Diaphragm
CGA/DISS Connection 678/636 678/636
Please Note: Not recommended for Epitaxial Deposition unless provided in 100SS or 10S(stainless steel) cylinders.

 

Molecular Weight:
101.01
Specific Volume:
3.83 cf/lb @ NTP
Boiling Point:
46.8°F @ 1 atm
CAS No.:
4109-96-0
Hazards:
Inhalation, Skin and Eye Contact, and Flammability
   
Safety Data: LC50 Rat: 314 ppm
Vapor Pressure Data:
  11.4 psia @ 32°F
23.7 psia @ 70°F

 

DICHLOROSILANE          
Cylinder Data/Size A B C 100SS  
Internal Volume (liters): 44 17 7 41  
Contents (lbs): 90 35 10 90  
Phase Break @ 70°F, 9 psig (lbs): 0.65 0.26 0.1 0.61  
RFO Size (inches): 0.020 0.030 0.040      
Maximum Flow (scf/h): 3.1 7 12.39      
Pressure (psia): 23.7          
DOT Label: White, Inhalation Hazard; Red, Flammable Gas; B&W, Corrosive Gas UN Number: UN 2189
DOT Class: 2.3 Cylinder: Steel alloy or stainless steel
Recommended OmniGas® Panels: Purgeable panel for low vapor pressure gases - Model No. 58PA200SVA-H with Hastelloy® Regulator - please inquire
Shelf Life: 1 year

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